Fluorescent chemosensors of carbohydrate triols exhibiting TICT emissions.
نویسندگان
چکیده
4-4'-Disubstituted biphenyl boronic acids (BBAs) are push-pull fluorophores with "turn-on" fluorescence properties. Upon carbohydrate triol binding, BBA boronate esters can participate in photon-induced electron transfer, giving a twisted intramolecular charge transfer (TICT) complex. The resulting TICT emissions distinguish between carbohydrates that bind to boron as a diol versus triol unit, thereby revealing stereochemical information about the carbohydrate.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 63 شماره
صفحات -
تاریخ انتشار 2015